Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
Preparation of Oxides, Glycols and Polyglycols from Lower Olefines. IV.
Preparation of Butylene Glycol
Hajime TOKUNOHiroaki YAMAMOTOAkira TAKATSUKI
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JOURNAL FREE ACCESS

1962 Volume 11 Issue 6 Pages 286-290

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Abstract
The authors contemplated to find the most suitable conditions to manufacture butylene glycol via chlorohydrin process.
It was found that a substantial good yield of Butylene chlorohydrin was obtained by utilizing natural circulating reaction tower using untreated electrolytic chlorine.
Further investigations were made on the dehydrochlorination of butylene chlorohydrin and it was found that butylene oxide was more easily isomerized to butylene aldehyde than propylene oxide to propion aldehybe.
In manufacturing butylene glycol by hydration of butylene oxide the optimum conditions on the concentration of butylene oxide, effect of isomers and other factors have been decided.
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© Japan Oil Chemists' Society
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