Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
Preparation of Maleic Mono-ester Salt
Anionic Surfactants Derived from Ethylene Oxide Adducts of s-Alcohols. I
Naoji KURATAKenji RAKUTANITakakiyo GOTO
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JOURNAL FREE ACCESS

1993 Volume 42 Issue 3 Pages 196-203

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Abstract
Monoesters from maleic anhydride and ethylene oxide adducts of C1214 s-alcohols (EOAA) were found in this study to be quantitative yield at a reaction temperature lower than 70°C with a sodium acetate catalyst. At a reaction temperature exceeding 100°C, the diesters formed by successive reaction lowered the yield of the monoesters. The present results were obtained by potentiometry for determination of total acid, maleic acid and monoster. The reaction kinetics are also discussed.
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