Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
4d-Shell Photoabsorption Spectra of Lanthanum- and Cerium-Halides
Shoji SuzukiTakehiko IshiiTakasi Sagawa
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1975 年 38 巻 1 号 p. 156-161

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The photoabsorption spectra of 4d electrons have been measured on LaF8, LaCl3, CeF3, CeCl8, and CeBr3 as well as on metallic La and Ce. The spectra consist of two parts. One is the line structure near the threshold and the other is the broad and intense band (giant band) following the line structure. The observed features of the spectra concerning the line structure are independent of halogen and in agreement with existing atomic theoretical calculations. On the other hand, the profile of the giant band in La-halides is dependent on halogen. The 3D1 line in La-halides is found to have an asymmetric line-shape. In the measurements by photographic method using synchrotron radiation, temperature dependence of the spectra is not detected.
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