Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
Effect of Hydrostatic Pressure on the Phase Transitions in K2ZnCl4
Kazuo Gesi
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1984 年 53 巻 1 号 p. 62-65

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Effect of hydrostatic pressure on the normal(I)-incommensurate(II)-ferroelectric(III) phase transitions in K2ZnCl4 was studied by differential thermal analysis and dielectric constant measurements. The I–II transition temperature (283°C at 0 GPa) increases with increasing pressure with a rate of 110 K GPa−1. The II–III transition temperature (the ferroelectric Curie temperature: 127°C at 0 GPa) decreases with an initial slope of −86.2 K GPa−1 as pressure increases. The results were compared with previously reported pressure effects of other K2SeO4-group ferroelectrics.

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