熱測定
Online ISSN : 1884-1899
Print ISSN : 0386-2615
ISSN-L : 0386-2615
解説
高性能熱電材料として期待されるハーフホイスラー化合物
黒崎 健 大石 佑治牟田 浩明山中 伸介
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ジャーナル フリー

2016 年 43 巻 3 号 p. 91-98

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抄録
Half-Heusler compounds such as MNiSn for n-type and MCoSb for p-type, M = Ti, Zr, Hf, show relatively high thermoelectric figure of merit (ZT = ∼0.8 for MNiSn and ∼0.5 for MCoSb) at 700–1000 K, thereby they are known as promising high-performance thermoelectric materials applicable for power generation devices in exhaust heat recovery systems of automobiles. Recently, the ZT values have been improved by applying various methods such as nanostructuring and band engineering, and ZT > 1 have been achieved in some half-Heusler compounds. In addition, a new p-type half-Heusler compound FeNbSb has been developed. In this review, we summarize the history of half-Heusler compounds as thermoelectric materials and review the representative results for their improved thermoelectric properties.
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© 2016 日本熱測定学会
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