高圧力の科学と技術
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
スクッテルダイト化合物の高圧合成と物性
高圧合成によるPrFe4Sb12の純良結晶作成とその特異な物性
田中 謙弥, 青木 英和
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ジャーナル フリー

2006 年 16 巻 4 号 p. 313-321

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抄録
For the filled skutterudite compounds, high-pressure synthesis is thought to be a powerful technique, because it is possible to synthesize compounds that could not been grown by the flux method under ambient pressure and to improve the filling factor of rare-earth ions. In this article, we report the details of high-pressure synthesis of the filled skutterudite PrFe4Sb12 and the brief result of its physical properties. As a result, we have succeeded in synthesizing high-quality crystals of PrFe4Sb12 with higher Pr-filling factor and obtaining information about the crystalline electric field of PrFe4Sb12.
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© 2006 日本高圧力学会
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