高圧力の科学と技術
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
特集 — 中性子を利用した高圧物性研究の新展開 —
マイクロエマルションの高圧 SANS, NSE 実験
長尾 道弘川端 庸平瀬戸 秀紀
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ジャーナル フリー

2009 年 19 巻 1 号 p. 52-61

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Small-angle neutron scattering (SANS) and neutron spin echo (NSE) spectroscopy have been used to elucidate static and dynamic structures of a microemulsion system composed of a nonionic surfactant, water, and oil. Using the contrast variation neutron scattering technique, static structure parameters are evaluated, and the molecular volume change with pressure is calculated. The bending elastic modulus increases with increasing pressure. This tendency is similar to the microemulsion system composed of anionic surfactant, water, and oil. Therefore, a universal feature of the surfactant membrane as a response to pressure is clarified, that is, the surfactant membrane becomes rigid at high pressure due to the increase of density of the hydrophobic tail of surfactant molecules and their aggregates.
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© 2009 日本高圧力学会
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