高圧力の科学と技術
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
熱測定で見た分子性物質のガラス転移
高圧下の実験を中心に
山室 修
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ジャーナル フリー

1999 年 9 巻 2 号 p. 117-125

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Our recent calorimetric studies on glass transition, especially for high pressure experiments, are reviewed in this article. The materials examined are molecular liquids with relatively simple molecular structure. The content of the article is as follows. (1) Introduction (2) Adiabatic Calorimeter under High Pressure (3) Configurational Entropy and Short-Range Ordering (4) Configurational Entropy and α Relaxation Time (5) Pressure Dependence of Glass Transition and Adam-Gibbs Theory. (6) Prigogine-Defay Ratio and Internal Parameter Theory (7) Structural Relaxation in (Volume) - (Internal Energy) - (Gibbs Energy) Space (8) Concluding Remarks
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© 日本高圧力学会
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