抄録
In shape memory polymers, large strain can be fixed at low temperature and thereafter can be recovered at high temperature. If the shape memory polymer is held at high temperature for a long time, the secondary-shape forming with irrecoverable strain appears. The secondary-shape forming can be applied to fabricate shape-memory polymer elements in a simple method. In the present paper, the influence of the strain-holding conditions on shape recovery and the secondary-shape forming in polyurethane-shape memory polymer is investigated by the tension test of film and the three-point bending test of sheet. The higher the shape-holding temperature and the longer the shape-holding time, the higher the rate of secondary-shape forming is. The equation to express the characteristics of secondary-shape forming is formulated.