散逸粒子動力学法を用いた界面活性剤水溶液の管内流れと自己集合に関する研究

抄録

A self-assembly research is currently one of the most studied branches of materials chemistry, therefore, has gained a lot of attention due to a variety of potential applications in electronics, engineering, biomedical, and optical fields. So far, many previous studies have been reported to investigate the self-assembly of surfactant for developing various functional materials. In this report, we focused on the chemical nature of the wall surface as a critical parameter which can drastically change the self-assembled structure. We have studied the rheological properties of surfactant solutions in the distinct chemical nanotubes using a computer simulation. We found that the difference in the viscosity is able to obtain depending on the chemical nature of the wall surface even if systems without the surfactant molecules. With the surfactant molecules, the characteristic viscosity behaviors were observed with rich steady-state morphologies. For example, although the concentration of surfactant is the same (c = 30%), completely different viscosity behaviors were seen in hydrophilic (shear-thinning) and hydrophobic (shear-thickening) nanotubes. Our simulation offers a guide to control the rheological properties of surfactant aqueous solutions by the chemical nature of the wall surface, the effect of confinement, concentration of surfactant aqueous solution and the self-assembled structure.