マイクロ・ナノ工学シンポジウム
Online ISSN : 2432-9495
セッションID: OS7-3-2
会議情報
OS7-3-2 塩化物フラックス法による一次元NiOおよびCeO_2結晶の育成(OS7 最先端材料が拓くマイクロ・ナノ工学の新展開(3))
櫻井 慶太我田 元湯葢 邦夫宍戸 統悦手嶋 勝弥大石 修治
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会議録・要旨集 フリー

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抄録
One-dimensional NiO and CeO_2 crystals were successfully grown by the cooling of chloride flux. NiCl_2・6H_2O or CeCl_3・nH_2O powders were used as the solute, and LiCl and KCl were chosen as the flux. The mixtures were heated to 700-900℃ for 10 h, and then cooled to 350℃ at rate of 200℃-h^<-1>. The NiO crystals had average sizes up to 481×3.65 μm. The morphology of the CeO_2 crystals clearly depended on the growth conditions, such as the holding temperature and Ce concentration. From X-ray diffraction pattern, the one-dimensional NiO and CeO_2 crystals elongated in the <100> directions.
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© 2012 一般社団法人 日本機械学会
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