素材物性学雑誌
Online ISSN : 1884-6610
Print ISSN : 0919-9853
ISSN-L : 0919-9853
チタン酸バリウムを主成分とする誘電体材料の電気的特性の安定性に及ぼす微細構造の影響
野村 武史佐藤 陽中野 幸恵
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1992 年 5 巻 1 号 p. 44-53

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Degradation of capacitance and insulation resistance under DC field has been studied with special reference to the microstructure of BaTiO3-based dielectric materials for Ni-electrode multilayer ceramic capacitors. The presence of dislocation loops, of which formation is pronounced by the low oxygen partial pressure of the ambient atmosphere during firing, has a deleterious effect on the life of insulation resistance under highly accelerated life testing. Tetragonality and the MnO-content are the decisive factors of the deterioration in capacitance under DC field. Dielectric materials composed of BaTiO3, MgO, CoO, MnO, and Ba0.4 Ca0.6 SiO3 showed superior stability in capacitance.
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