素材物性学雑誌
Online ISSN : 1884-6610
Print ISSN : 0919-9853
ISSN-L : 0919-9853
バルーン状スピネルフエライトの作製と表面組織の制御
上田 みどり嶋田 志郎稲垣 道夫
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1994 年 7 巻 2 号 p. 46-51

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Spinel type ferrites of ZnFe2O4 and NiFe2O4, and also α-Fe2O3 with balloonshape were prepared by coating the ethylene glycol (EG) solution of correspondingmetal chlorides onto carbon balloons with size of 53-75μm and heating upto 950°C in the flow of oxygen. The ZnFe2O4 balloons prepared by a solid-statereaction between the balloons of α-Fe2O3 and ZnO had a characteristic wavylinesurface texture, though those prepared directly from the mixed EG solutionof ZnCl2 and FeCl3 had smooth surfaces. The NiFe2O4 balloons were preparedfrom the mixed solution of NiCl2 and FeCl3.
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