Experimental study has been conducted to produce the carbon dioxide hydrate in emulsions for improving a fluidity of the hydrate slurry. Water in oil emulsions composed of dimethyl silicon oil and purified water doped with a small amount of surfactant were prepared by briskly mixing of homogenizer. Carbon dioxide absorption and hydrate production experiment was carried out for various water content and surfactant conditions at 275K under 3.0MPa. The results show that the carbon dioxide hydrate in fine water droplet dispersed in silicone oil was successfully produced. Effect of water content and surfactant solvent in silicone oil was also revealed.