材料
Online ISSN : 1880-7488
Print ISSN : 0514-5163
ISSN-L : 0514-5163
論文
水素化アモルファスシリコンの表面酸化起因真性応力の分子動力学解析
田村 陽平高本 聡今泉 俊介齋藤 玲子伊藤 祥代波田野 明日可泉 聡志
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2017 年 66 巻 12 号 p. 950-956

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It was reported that the lack of the structural stability of semiconductor silicon micro-pattern induced the lateral undulation buckling. Our previous report revealed that the intrinsic stress of the oxide film on the surface of amorphous silicon produced the compressive stress which induces the buckling failure. However, actual amorphous silicon contains hydrogen atoms. Therefore, in this study, we realize the surface oxide film fabrication on hydrogenated amorphous silicon and clarify the relationship between hydrogen concentration and intrinsic stress due to surface oxidation. As a result, regardless the hydrogen concentration, surface oxide layer contains no hydrogen atoms. In addition, it is found that the intrinsic stress is generated in the sub-oxide layer where oxidation process is not completed. As the hydrogen concentration increases, the integral value of the compressive stress decreases linearly. The stress decreases about 30 % when the hydrogen concentration reaches 25 at%. Decrease in the stress would be caused by the sparse silicon structure due to hydrogen atoms and resulting release of the strain due to surface oxidation.

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