高密度ポリエチレンと超高分子量ポリエチレンのブレンドの分散および劣化挙動に及ぼす混練条件の影響

抄録

High density polyethylene (HDPE) / ultra high molecular weight polyethylene (UHMWPE) blend is expected as an all-polyolefin recycle material that can achieve both mechanical properties and a continuous melt-mixing process. In order to improve the mechanical properties of polymer blends, optimal mixing is required to achieve both good dispersibility and low degradation. In this study, the effect of mixing conditions on the dispersion and degradation behavior of HDPE/UHMWPE blends were investigated. Neat HDPE and HDPE with 5% UHMWPE were obtained by melt mixing in internal batch mixer. Time of mixing, Specific Energy Input (SEI), and rotation speed of the rotors were changed. From the results of microscopic observation and a differential scanning calorimetry (DSC), the dispersibility progressed with the increase in SEI regardless of the rotor speed. The results of Gel Permeation Chromatography (GPC) show the molecular chain scission was also promoted by the increase in SEI. In the other hands, the results of oscillatory shear test show the increase in storage modulus G’ were promoted by increase in not only SEI but rotor speed. Furthermore, the molecular chain scission and increase in G’ were significantly suppressed by the nitrogen atmosphere.