材料
Online ISSN : 1880-7488
Print ISSN : 0514-5163
ISSN-L : 0514-5163
高温高圧下における硫化カドミウムの電気伝導度
大杉 治郎清水 澄中村 登紀男小野寺 昭史
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1968 年 17 巻 172 号 p. 47-51

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The electrical resistance of a single crystal of cadmium sulfide was measured at pressures up to 40kbar and at temperatures up to 700°C in a cubic compact anvil high pressure apparatus.
The electrical conductivity of CdS of either the atmospheric wurtzite phase or the high-pressure rock salt phase is semiconductive. In the high-resistivity samples used in the present experiment the electrical resistance increased with pressure in either phases, the wurtzite or the rock salt. From the measurements of electrical resistance as a function of temperature, it is found that a band gap of CdS of the wurtzite phase is about 2.5eV. For the CdS of the rock salt phase a band gap of about 0.8eV is obtained.
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