抄録
Acrylonitrile-acrylic elastomer-styrene terpolymer (AAS resin) was developed to improve weatherability of acrylonitrile-butadiene-styrene terpolymer (ABS resin). To compare thermal stability of both resins, test pieces of AAS and ABS resins were injection molded at various temperatures and the Izod impact value of the resulting moldings was measured. A study was then made to find the relationship between this value and deterioration of the resins. AAS resin was molded at temperatures from 180°C to 280°C. The impact value of the resulting moldings was almost constant for temperatures up to 260°C, with the first major decrease occuring at 280°C. In contrast, the impact value of conventional ABS resin moldings constantly decreased as the molding temperature elevated. To explain this phenomenon in the both resins, two types of test program steps were undertaken:
(1) The cause of the change in characteristics of the AAS resin was first determined by: obtaning its stress-strain curve in a high-speed flexural strength test; measuring its infrared absorption spectrum; and determining its flow properties with a constant-pressure extrusion type rheometer;
(2) The distribution of elastomer in the resin was observed with an electron microscope. It was found that the decrease of impact values of both resins at high temperatures is caused by deterioration of the elastomer. Also, it was found that the different relationships between the impact value and molding temperatures for AAS and ABS resins are due to the difference between the rates of thermal degradation of the acrylic elastomer and butadiene elastomer.
