スマートプロセス学会誌
Online ISSN : 2187-1337
Print ISSN : 2186-702X
ISSN-L : 2186-702X
デンドライト格子構造を有する固体電解質の光造形と アルミニウム製錬への応用検討
高橋 昌也桐原 聡秀
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2021 年 10 巻 4 号 p. 274-278

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Ceramic electrodes with dendritic lattice patterns were fabricated successfully by stereolithographic additive manufacturing (STL-AM). Solid electrolytes of yttria and scandia stabilized zirconia(YSZ and SSZ)were selected to oxygen separation in molten salt electrolysis for aluminum refining without carbon dioxide excretions. In the graphic design of dendrite patterns, the cylinder lattices were connected at 4, 6, 8 and 12 in coordination numbers, and the aspect ratio were optimized to obtain maximal specific surfaces. Spatial profiles of high temperature liquid propagations in dendritic patterns were visualized systematically by computer fluid dynamics(CFD). The zirconia particles were dispersed into a photo sensitive resin to obtain the paste materials for the STL process. An ultraviolet laser beam was scanned on the spread paste to create two-dimensional (2D)cross sections. Through layer laminations and interlayer bonding, three-dimensional (3D)objects with dendritic structures could be fabricated. The composite precursors were dewaxed and sintered in the air atmosphere to obtain fine ceramic microstructures.
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