In-situ studies of the competitive adsorption of lubricant additives

Abstract

We present a study on the adsorption of corrosion inhibitors, anti-wear additives and friction modifiers from a synthetic and a mineral base oil on metal (Fe2O3) surfaces. In order to obtain quantitative and spatial data during the adsorption process we set up a combined quartz crystal microbalance (QCM-D) and confocal scanning laser microscope (CLSM). In addition to QCM-D and CLSM, also a UHV-tribometer was used to study the performance of gas phase deposited additives films without environmental interferences. In combination with macroscopic performance tests using a “ball-on-three-plates-tribometer” and corrosion tests, the adsorption, the morphology and the mechanical properties of the additives were correlated with their performance.