日本機械学会論文集A編
Online ISSN : 1884-8338
ISSN-L : 1884-8338
一般論文
SOFC作動環境下におけるNi-YSZ系アノード材料の機械的特性
北原 大道井口 史匡奥田 倫也佐多 教子川田 達也湯上 浩雄
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2012 年 78 巻 792 号 p. 1198-1207

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Mechanical properties of Ni-YSZ cermet (Ni 30, 44, 58 vol.%) in SOFC operating conditions in the temperature range of room temperature to 1000°C and in reduction atmospheres, were studied by an in situ four points bending method. Ni30 specimens in the whole testing temperature and Ni44, Ni58 specimens at the temperature lower than 350 °C fractured brittly, and Ni44, Ni58 specimens fractured with plastic deformation at the temperature higher than 350 °C. In the microstructure of three Ni contents, nickel was aggregated and isolated in Ni30 specimens. By contrast, nickel was well distributed in Ni44, 58 specimens. In addition, the yield strength of nickel decreases at the temperatures higher than 300 °C. Hence, observed results suggested being due to the local yield of well distributed nickel in the cermet. Because anode supported type SOFCs employ Ni-YSZ cermet, which nickel content is higher than 44 vol.%, this study suggests that an irreversible deformation occur during SOFC operation due to the plastic deformation of Ni-YSZ cermet.

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