両親媒性カチオンブロック共重合体が塩化ナトリウム存在下において形成するシダの葉状モルフォロジー

抄録

An unsymmetric diblock copolymer b-Q57A97 of (ar‑vinylbenzyl)trimethylammonium chloride (Q) and N,N-dimethylvinylbenzylamine (A), synthesized by reversible addition-fragmentation chain transfer radical polymerization, and its molecular assemblies were characterized by static and dynamic light scattering and steady state fluorescence using N-phenyl-1-naphthylamine (PNA) as a probe. Scanning electron microscopy observations indicated that b-Q57A97 formed a unique fern leaf-like morphology in the presence of NaCl.