Journal of the Mass Spectrometry Society of Japan
Online ISSN : 1880-4225
Print ISSN : 1340-8097
ISSN-L : 1340-8097
報文
A New Matrix System in Fast Atom Bombardment Mass Spectrometry of Prenylated- and Geranylated-Phenolic Compounds
Mitsuo TakayamaToshio FukaiYoshio HanoTaro Nomura
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ジャーナル フリー

1990 年 38 巻 2 号 p. 77-85

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抄録
A 1 : 1 (v/v) mixture of m-nitrobenzyl alcohol (m-NBA) and 2,2'-dithiodiethanol (DTDE, HOCH2CH2SSCH2CH2OH) was applied as a new matrix system to FAB mass spectra of prenylated- and geranylated-phenolic compounds, with which the matrix was relatively involatile and durable for a long period of time. This resulted in the good reproducibility of the FAB spectra. The FAB spectra were compared with the corresponding EI and CI mass spectra. The FAB spectra gave the intense molecular ions M and the fragment ions.
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© 1990 by The Mass Spectrometry Society of Japan
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