MATERIALS TRANSACTIONS
Online ISSN : 1347-5320
Print ISSN : 1345-9678
ISSN-L : 1345-9678
Preparation and Magnetic Properties of Co-based Bulk Glassy Alloys
Hisato KoshibaAkihisa Inoue
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2001 Volume 42 Issue 12 Pages 2572-2575

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Abstract

This paper deals with the formation and soft magnetic properties of Co(Fe)-M-B (M=transition Metals) glassy alloys in thin sheet and bulk ring forms prepared by single role melt spinning and copper mold casting methods. This multicomponent system was found to exhibit a distinct glass transition and a wide supercooled liquid region (ΔTx) exceeding 70 K before crystallization. The high thermal stability of the supercooled liquid has enabled us to produce the bulk glassy alloys. The Co–Fe–Ta–B alloy samples with a ring form of φ7 mm×φ3 mm×t1 mm consist of a single glassy phase. These bulk amorphous samples exhibit excellent soft magnetic properties, which are nearly the same as those of the corresponding melt-spun glassy thin sheets: the coercivity (Hc) and saturation magnetic flux density (Bs) are 0.25 A/m and 0.49 T, respectively. These good soft magnetic properties suggest structural homogeneity resulting from its high glass-forming ability. The excellent soft magnetic properties are useful for industrial application.

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© 2001 The Japan Institute of Metals and Materials
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