MATERIALS TRANSACTIONS
Online ISSN : 1347-5320
Print ISSN : 1345-9678
ISSN-L : 1345-9678
Preparation of Thick Functionally Graded Layers of Ceramics by Surface Modification of Tantalum and Titanium Using High Temperature Plasma Processing
Masanobu NunogakiMasahiro InoueKatsuki Kitahama
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2001 Volume 42 Issue 3 Pages 457-459

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Abstract

Surfaces of metals, such as Ta and Ti, have been changed successfully to a new type of ceramic layers having the compositional gradient by means of the plasma processing at high temperature above 900°C. Surfaces of Ta and Ti were transformed to thick layers of ceramics, i.e. TiC, TiN, TaC or TaN components, respectively, by carburizing or nitriding. Resultantly, a Vicker’s hardness of each modified sample surface remarkably increased over 3000 kg/mm2. The density of carbides or nitrides in the modified layer and at the interface was measured to decrease with depth. The width of interface was wide about 7 \\micron, in the case of TiC . Additionally, the irradiation of 20 MeV-electron beam to samples as the pretreatment before the plasma processing was effective to increase the thickness of modified layer.

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© 2001 The Japan Institute of Metals and Materials
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