MATERIALS TRANSACTIONS
Online ISSN : 1347-5320
Print ISSN : 1345-9678
Synthesis and Thermoelectric Performance of (Bi0.25Sb0.75)2Te3 Polycrystals Dispersed with Ag and BN
Liu Xue-DongYong-Ho Park
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2002 Volume 43 Issue 1 Pages 30-35

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Abstract

Mechanical alloying followed by pulse-discharge sintering (MA-PDS) is used to fabricate bulk (Bi0.25Sb0.75)2Te3 polycrystals dispersed with metal Ag, ceramic BN or both. During sintering, the dispersed second phase particles, especially BN, effectively hinder the growth of the (Bi, Sb)2Te3 matrix phase, giving rise to a refined microstructure in compacts. Property measurements demonstrate that the metal Ag is effective in raising electrical conductivity, while the ceramic BN is effective in decreasing thermal conductivity through reinforced phonon scattering. By adding Ag alone, we have identified a large potential for further improving the room-temperature figure of merit of the (Bi0.25Sb0.75)2Te3 mother alloy. The maximum figure of merit appears at 0.02 mass% Ag with value in the order of 3.4×10−3 K−1, which is 18% higher than that of the mother alloy. This result is of practical significance. Because of the deterioration of Seebeck coefficient, addition of BN either alone or in combination with Ag does not produce a favorable figure of merit.

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© 2002 The Japan Institute of Metals and Materials
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