Hydrogen-Storage Properties and Structure Characterization of Melt-Spun and Annealed Mg-Ni-Nd Alloy

抄録

The hydriding/dehydriding characteristics of a Mg-rich Mg–Ni–Nd alloy produced by melt-spinning and subsequent annealing have been investigated. This alloy absorbs ∼ 4.7 mass% hydrogen (H⁄M∼ 1.5) quickly between 423 and 573 K and wholly desorbs it at moderate speeds above 453 K. Transmission electron microscope observations and selected-area electron diffraction analyses of this alloy before and after hydriding demonstrate that it consists of multiple phases of Mg₂Ni and Nd-hydride precipitated uniformly in a nano-structured Mg matrix. The fast reaction kinetics is caused by an interplay between a catalytic action of the Nd-hydrides and the surrounding nano-sized Mg grains which quickly store or evolve hydrogen across the interfaces.