MATERIALS TRANSACTIONS
Online ISSN : 1347-5320
Print ISSN : 1345-9678
ISSN-L : 1345-9678
Effect of Aging Time on Shape Memory Properties of Sputtered Ni-rich Ni2MnGa Alloy Films
Motohiko SuzukiMakoto OhtsukaMinoru MatsumotoYasukazu MurakamiDaisuke ShindoKimio Itagaki
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2002 Volume 43 Issue 5 Pages 861-866

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Abstract

Ni2MnGa alloy is an intelligent material with ferromagnetic and shape memory properties. The application of the alloy films to micro-actuators has been proposed. The Ni-rich Ni2MnGa alloy films with a thickness of nearly 5 \\micron were deposited on Al2O3 substrates by a radio-frequency magnetron sputtering apparatus using a Ni52Mn24Ga24 target. They were heat-treated at 1073 K for 36 ks for homogenization and ordering. The martensitic transformation temperatures of the heat-treated films were higher than room temperature. To investigate the effect of aging time on shape memory properties, the heat-treated films were aged at 673 K for various times between 0.9 and 57.6 ks in a constrained condition. The constraint-aged films showed the two-way shape memory effect by thermal cycling. Fine precipitates with a crystal structure of L12 were observed in the constraint-films aged for a long period. As for their two-way shape memory properties, a range of transformation temperature narrowed and the amount of macroscopic shape change increased with increasing aging time.

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© 2002 The Japan Institute of Metals and Materials
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