2004 Volume 45 Issue 10 Pages 2987-2993
The modified sessile drop method (MSDM) and the modified pycnometric method (MPM) have been employed to measure precisely the densities of liquid nickel-based ternary (Ni-Co-Al) and quaternary (Ni-Co-Al-Cr, Ni-Co-Al-Mo, Ni-Cr-Al-Mo) alloys and four commercial superalloys in liquid and mushy states. There was a good agreement between the values measured by the two methods. The measured densities of liquid model alloys and commercial superalloys in liquid and mushy states decreased linearly with increasing temperature for the experimental temperature range. The temperature coefficient of the density of liquid ternary Ni-Co-Al alloys measured in this work can be represented as a quadratic function of the aluminium concentration in the alloys. The density of liquid Ni-Co-Al alloys can be expressed as a function of both temperature and aluminium concentration in the alloys. The recommended equations for the densities of liquid nickel-based ternary and quaternary alloys and four commercial superalloys in liquid and mushy states were obtained by analysing density values measured by both MSDM and MPM. The calculated values from the recommended density equations show good agreement with those measured by both MSDM and MPM.