MATERIALS TRANSACTIONS
Online ISSN : 1347-5320
Print ISSN : 1345-9678
ISSN-L : 1345-9678
Dehydriding Property of NaBH4 Combined with Mg2FeH6
Guanqiao LiMotoaki MatsuoStefano DeleddaBjørn C. HaubackShin-ichi Orimo
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2014 Volume 55 Issue 8 Pages 1141-1143

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Abstract

The dehydriding property of xNaBH4 + (1 − x) Mg2FeH6 (x = 0.1–0.75) is measured to investigate the effect of combining with complex hydride Mg2FeH6 on reducing dehydriding temperature of metal borohydrides, which has lately been found to be effective for LiBH4. When x = 0.1 and 0.125, a single-step dehydriding reaction is observed, while in the composition range x ≥ 0.25, a multi-step dehydriding reaction is observed. Despite the different dehydriding process, X-ray diffraction measurements confirmed that Mg2FeH6 and NaBH4 began releasing hydrogen simultaneously over the entire composition range. The results also indicate that the dehydriding temperature of NaBH4 is reduced by at least 150 K when combining with Mg2FeH6.

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© 2014 The Japan Institute of Metals and Materials
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