2022 Volume 63 Issue 4 Pages 522-528
This study investigates the acoustic properties of a metal near its phase-change temperature using laser ultrasonics. A Pb-free solder sample was prepared, and its temperature was increased stepwise from 40°C to 210°C with concurrent measurement of laser ultrasonic waves on the solder surface. Noticeable change in the waveforms was observed at 203°C and 209°C. These sudden changes occurred with a 1°C change in temperature. The change at 203°C was attributed to an acoustic mode transformation from Rayleigh-like to Lamb-like as we also found that part of the solid solder became thin as a result of partial melting from the bottom and rim. Only the sound through the air was detected at temperature of 209°C and higher, where this sound was due to ablations. This phenomenon was responsible for local melting at the laser irradiation point, generating the ultrasonic waves.