Investigation of Relationship between Corrosion and Hydrogen Entry Behavior of Electro-Galvanized Steel under Atmospheric Environment

Abstract

The effect of corrosion status of zinc coating on the hydrogen absorption behavior was investigated. Dry-wet corrosion test was conducted after applying NaCl solution to the zinc coated steel sheets. The permeating hydrogen during the corrosion test was measured by electrochemical technique. It was found that the hydrogen permeation was not observed at early stage of corrosion while significant hydrogen permeation was observed at middle stage of corrosion. Then, the hydrogen permeation decreased gradually at later stage of corrosion. In order to clarify the mechanism of this behavior, surface morphologies of corroded specimens were analyzed by Electron Probe Micro Analyzer. It was found that the hydrogen permeation was observed when the steel substrate was partially appeared, indicating that galvanic corrosion is related to the hydrogen permeation.

 

This Paper was Originally Published in Japanese in Zairyo-to-Kankyo 71 (2022) 218–224. The description of the second eq. (1) is slightly modified.

Fig. 13 Schematic for hydrogen absorption behavior in galvanized steel with transition of corrosion process.