MATERIALS TRANSACTIONS
Online ISSN : 1347-5320
Print ISSN : 1345-9678
ISSN-L : 1345-9678
Microstructure of Materials
Phase Equilibria in Aluminium–Ruthenium–Silicon System near 1200 Kelvin
Koichi KitaharaHiroyuki TakakuraYutaka IwasakiKaoru Kimura
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2024 Volume 65 Issue 1 Pages 18-26

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Abstract

A narrow-gap semiconductor with a complex crystal structure was recently discovered in the Al–Ru–Si system. To determine the homogeneity range of the semiconductor phase and further discover new phases, phase equilibria in the Al–Ru–Si system near 1200 K were investigated through prolonged-annealing experiments. Eleven new ternary phases including two incommensurate composite-crystalline and an icosahedral quasicrystalline phases were identified using powder and single-crystal X-ray diffraction, and their compositions at two-phase and three-phase equilibria were evaluated by means of electron-probe X-ray microanalysis. On the basis of the data obtained in this study and those adopted from the literature, a tentative isothermal section of the Al–Ru–Si equilibrium phase diagram near 1200 K was drawn.

Tentative isothermal section of the Al–Ru–Si equilibrium phase diagram near 1200 K. Fullsize Image
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