NO + CO Reaction on Polycrystalline Palladium Foils with Specific Surface Crystallographic Orientation: A New Approach to Develop Foil Catalysts Based on Texture Control

Kenta Hayashi; Satoshi Kameoka; An-Pang Tsai

doi:10.2320/matertrans.MT-M2021050

This article has now been updated. Please use the final version.

NO + CO Reaction on Polycrystalline Palladium Foils with Specific Surface Crystallographic Orientation: A New Approach to Develop Foil Catalysts Based on Texture Control

Kenta Hayashi, Satoshi Kameoka, An-Pang Tsai

Author information

Keywords: foil catalyst, texture control, surface crystallographic orientation, structure sensitivity, palladium catalyst, NO + CO reaction, electron backscattered diffraction, material gap

JOURNAL FREE ACCESS Advance online publication

Article ID: MT-M2021050

DOI https://doi.org/10.2320/matertrans.MT-M2021050

The final version of this article is now available: Vol. 62 (2021), No. 8 pp. 1089-1096

Details

Abstract

Catalytic properties of the metal foils were tuned by the specific surface crystallographic orientation control. The NO + CO reactivity of polycrystalline Pd foils with (101) or (211) orientation, characterized by using electron backscattered diffraction (EBSD), was investigated. The (211)-oriented Pd foils exhibited much greater activity compared with (101) orientated Pd foils, which is in good agreement with the previous structure sensitivity studies on NO + CO reactions over Pd. Hence, the present study introduces the surface crystallographic orientation control of foil catalysts as a new development strategy for the unique catalysts in the material gap.

Fullsize Image

Corresponding author

Register with J-STAGE for free!