Transactions of the Japan Institute of Metals
Online ISSN : 2432-4701
Print ISSN : 0021-4434
ISSN-L : 0021-4434
Thermodynamic Studies of Tl-Bi Liquid Alloys
Osamu MikuniMitsuo ShimojiKichizo Niwa
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1961 年 2 巻 4 号 p. 210-212

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The e.m.f. of the cell Tl(l)/TlCl in KCl-LiCl/Ti-Bi(l) was measured over the temperature range of 370° to 480°C. The activity curve shows a profoundly negative deviation from Raoult’s law. The excess thermodynamic functions were calculated from the activity data obtained. Theoretical consideration was given for the excess functions of this system.
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© The Japan Institute of Metals
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