Journal of the Society of Inorganic Materials, Japan
Online ISSN : 2185-4378
ISSN-L : 1345-3769
フルクトース水溶液中での焼成ドロマイトの水和とその水和物による塩化水素ガス除去
小嶋 芳行金子 貞之安江 任
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ジャーナル フリー

2006 年 13 巻 321 号 p. 98-104

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This study was made to investigate the characterization and HC1 gas removal of calcined dolomite hydrate (mixture of Mg (OH) 2 and Ca (OH) 2) synthesized by hydrating the calcined dolomite with water contained fructose. The calcined dolomite hydrate with ultrafine particles was synthesized by adding fructose solution to the calcined dolomite which was heated the dolomite at 1000°C for 1 hour. The sample was characterized by means of X-ray diffraction, measurements of specific surface area and particle size distribution.
The limestone, which was contained in the dolomite, was dissolved using 0.10 mol dm-3 HC1 solution. The calcined dolomite was obtained by heating the treated dolomite at 1000°C for 1 hour. The calcined dolomite hydrate with ultrafine particle was synthesized by hydrating the calcined dolomite using fructose solution for 6 h, and was a mixture of Ca (OH) 2 and Mg (OH) 2. The specific surface area of the calcined dolomite hydrate increased with the increase of fructose/calcined dolomite mass ratio. In fructose/calcined dolomite mass ratio of 0.07, the specific surface area of the calcined dolomite hydrate was 147 m2·g-1 Ca (OH) 2 and Mg (OH) 2 were uniformly dispersed in sample. The HC1 gas removal ability of the calcined dolomite hydrate was enhanced with increase of specific surface area.
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