シクロデキストリン存在下におけるアゾメチン化合物の半波還元電位
1974 年 1974 巻 12 号 p. 2440-2442
詳細
1974 年 1974 巻 12 号 p. 2440-2442
As one of studies on the effect of proton donor on the half-wave reduction potential, DC polarographic behavior of N-benzylideneaniline (BA) and N- (diphenylrnethylene) aniline (DA) was investigated in DMF solution in the presence of cx-cyclodextrin (CD) by the three-electrode system. The half-wave reduction potential of the 1 at wave shifted to a less negative potential (100-150 mV) by the addition of CD. As a most plausible interpretation on the results, the formation of hydrogen bond was suggested between BA or DA and CD.
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