1977 年 1977 巻 1 号 p. 141-143
[1-(Trifluoromethyl)tetrafluoroethoxy]acetonitrile, which was derived from chloroacetonitrile and hexafluoroacetone with potassium fluoride, was hydrolyzed easily to give the corresponding amide [4] and acid (5).
The solubility and pKa of [1-(trifluoromethyl)tetrafluoroethoxy]acetic acid 5 were determined as 1.34 al and 2.83, respectively, showing that (5) is much less soluble in water than chloro- and cyanoacetic acids with similar acidity.143
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