ジメチルスルホキシド中におけるビス(トリフルオロアセチルアセトナト)ニッケル(II)の溶液内平衡
1984 年 1984 巻 8 号 p. 1341-1344
詳細
1984 年 1984 巻 8 号 p. 1341-1344
The chemical equilibria of bis(trifluoroacetylacetonato)nickel(II) in dimethyl sulfoxide were studied on the basis of the concentration dependence of UV spectrum, the molar conductivity curve, and the d. c. polarographic behavior. The chemical equilibria considered were
[Ni(bi-tfac)2]⇔ [Ni(bi-tfac)(uni-tfac)] ⇔Ni(tfac)++tfac-,
where bidentate and unidentate are abbreviated as bi- and uni-, respectively. The chemical equilibria shifted upon the addition of supporting electrolyte, O.05 mol·dm-3 TBAP.
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