1990 Volume 37 Issue 12 Pages 953-958
ω-Methylthioalkyl and ω-methylsulfinylalkyl isothiocyanates have been known to contribute to the characteristic flavor of fresh wasabi. We studied on the change and stabilization of these compounds during freeze concentration of freeze-milled wasabi and horse radish. ω-Methylsulfinylalky1 isothiocyanates are possibly produced by enzymecatalyzed oxidation from ω-methylthioalkyl isothiocyanates and/or ω-methylthioalkyl glucosinolates in wasabi. We discussed on suitable enzyme reaction conditions for wasabi and reasonable biosynthetic pathway of ω-methylsulfinylalkyl isothiocyanates in it.