ソノケミストリー討論会講演論文集
Online ISSN : 2424-1512
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19. 超音波を活用した酢酸銅(II)/酢酸マンガン(III)による置換フェノール類の酸化反応
滝沢 靖臣小海 美穂子大河内 正一
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p. 71-73

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Various substituted phenols were oxidized with copper(II) acetate and manganese (III) acetate using ultrasonic irradiation. 2-Substituted-4-silyloxyphenols were oxidized in benzene to give the corresponding dimers which were coupled at C-C or C-O atoms. 2-t-Butyl-4-silyloxyphenols was oxidized with manganese (III) acetate in acetic acid using ultrasonic irradiation to give C-O coupling quinone dimer and C-C coupling dimer, respectively. The effect of ultrasonic irradiation was observed for the yield in this oxidation reaction.
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© 1998 日本ソノケミストリー学会
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