日本セラミックス協会 年会・秋季シンポジウム 講演予稿集
16th Fall Meeting of The Ceramic Society of Japan & The 5th International Meeting of Pacific Rim Ceramic Societies(PacRim5)
セッションID: 05-O-08
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Effect of Samarium Oxide Addition on Electrical Resistivity of Hot-Pressed Aluminum Nitride
*Jun YOSHIKAWAYuji KATSUDANaohito YAMADAChikashi IHARAMasaaki MASUDAHiroaki SAKAI
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The electrical resistivity of hot-pressed AlN with 0.1 to 4.8 wt% Sm2O3 addition was investigated. A minimum of 0.5wt% Sm2O3 addition decreases the resistivity of AlN ceramics at room temperature from more than 1014 ohm-cm to the range of 1010 to 1012 ohm-cm. The activation energy of the resistivity is around 0.3 eV, which is about half that of AlN with Y2O3 addition with a resistivity in the same range. SPM and EPMA analyses showed that the conductive path was a grain boundary phase composed of Sm, Al, and O, which formed a three-dimensional network structure. This AlN ceramics with Sm2O3 addition has the feature that its electrical conduction behavior is characterized by a small amount of the grain boundary phase.
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© The Ceramic Society of Japan 2003
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