Original Articles
Molecular chirality: A new approach from a dynamical point of view
2017 年 93 巻 10 号 p. 841-849
詳細
2017 年 93 巻 10 号 p. 841-849
The double minimum potential (DMP), which Hund assumed to explain the quantum-mechanical stability of enantiomers, was discussed, by citing three typical examples of DMP: inversion, internal rotation, and puckering. They expanded the classical scope of chirality, as defined by Kelvin, and indicated that a new bridge could be formed between the three low-frequency DMP modes and the asymmetric syntheses of chiral molecules.
