Phosphorus Research Bulletin
Online ISSN : 1882-2363
Print ISSN : 0918-4783
ISSN-L : 0918-4783
SYNTHESIS AND PHOTOCHEMICAL PROPERTIES OF MICACEOUS CERIUM PHOSPHATES
Tsugio Sato, Ruixing Li, Chigusa Sato, Shu Yin
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ジャーナル フリー

2007 年 21 巻 p. 44-47

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抄録
Micaceous hydrated cerium phosphate, Ce2(PO4)2HPO4•H2O, was prepared by the hydrothermal reaction and its photochemical properties were evaluated. Ce2(PO4)2HPO4•H2O showed excellent absorption ability of light having a wavelength less than 450 nm of wavelength and oxidation catalytic activity lower than undoped ceria. Ce2(PO4)2HPO4•H2O was converted to a plate-like CePO4-CeP2O7 mixture around 650°C and CePO4-CeP3O9 mixture around 800°C, possessing absorption ability of UV light less than 400 nm and much lower oxidation catalytic activity than Ce2(PO4)2HPO4•H2O.
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© 2007 Japanese Association of Inorganic Phosphorus Chemistry
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