Phosphorus Research Bulletin
Online ISSN : 1882-2363
Print ISSN : 0918-4783
ISSN-L : 0918-4783
THE SYNTHESIS AND THERMAL PROPERTIES OF TRIAMMONIUM CYCLO-TRI-μ-IMIDO-TRIPHOSPHATE
MAKOTO SAKURAIMAKOTO YASUIHIROKAZU SUZUKIMIOKO MAEDAMAKOTO WATANABE
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ジャーナル フリー

1999 年 9 巻 p. 103-106

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抄録
Triammonium cyclo-tri-μ-imido-triphosphate monohydrate has been prepared by adding ethanol into a mixture of cyclo-tri-μ-imido-triphosphoric acid and ammonia water. When the triammonium cyclo-tri-μ-imido-triphosphate was heated, release of the water of crystallization was observed and no decomposition of the imidophosphate occurred up to 145°C. The imidophosphate decomposed to produce many kinds of condensed phosphates with or without NH and NH2 groups at a temperature higher than 145°C. The sample finally changed to phosphoric acid and oligophosphates including amino and imino groups.
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© Japanese Association of Inorganic Phosphorus Chemistry
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