Review of Polarography
Online ISSN : 1884-7692
Print ISSN : 0034-6691
ISSN-L : 0034-6691
Kinetics and Mechanism of Polarographic Reduction of Rhodamin B
S.K. JHAS.N. SRIVASTAVA
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1970 年 16 巻 5 号 p. 103-108

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Polarographic reduction of Rhodamin B has been carried out in Britton Robinson and Mcllvaine buffers. The value of n computed from experimentally determined D and subsequent application of llkovic equation and E3/4-E1/4 values conclusively prove that the electrode process is irreversible. k, the rate constant, αnα the product of transfer coefficient and electrons involved in the activation process and δG≠ the energy of activation have been calculated. Attempts have also been made to estimate value of na alone and to give mechanism of the electrode process.
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© The Polarographic Society of Japan
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