金属表面技術
Online ISSN : 1884-3395
Print ISSN : 0026-0614
ISSN-L : 0026-0614
イミノニ酢酸を錯化剤とする銅無電解めっき
大野 湶戸田 崇文今井 弘向 正夫
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1976 年 27 巻 11 号 p. 607-610

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A new electroless copper plating bath containing iminodiacetic acid as a complex agent has been developed and applied to the plating on the sintered PbTiO3-PbZrO3 ceramic substrate. The deposition rate of copper onto ceramics from the new type bath was compared with that from the different baths containing EDTA or Rochelle salt as a function of plating time, pH value and formaldehyde concentration. It was found that the iminodiacetate bath composed of 0.026M copper sulfate, 0.12M iminodiacetic acid and 0.5M formaldehyde at pH12.5, gave a maximum deposition rate which was twice that in EDTA bath and six times that in Rochelle salt bath. Effects of stirring the electroless plating bath and various metallic substrate surfaces on the copper deposition rate were also discussed.
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