常温型溶融塩浴からのNb-Al合金の電析
1994 年 45 巻 8 号 p. 805-809
詳細
1994 年 45 巻 8 号 p. 805-809
An investigation has been conducted into the deposition of Nb-Al alloy from ambient-temperature molten salt electrolytes of AlCl3-NbCl5-BPC and AlCl3-Nb3Cl8-BPC. The results obtained are as follows.
(1) An Nb-Al alloy deposit was obtained from an AlCl3-NbCl5-BPC melt of low NbCl5 content.
(2) The valence of the Nb (V) ion in the melt was reduced by the addition of Al powder. In this case, an Nb-Al alloy deposit was obtained from melts with a higher NbCl5 content than in (1) above.
(3) An Nb-Al alloy of 29.3wt% Nb was deposited from a 1.0AlCl3-0.90NbCl5-1.0BPC melt with Al powder (3.0wt%) and 50vol% toluene at 40mA/cm2 and 90°C.
(4) An Nb-Al alloy of 23.8wt% Nb was deposited from a 1.3AlCl3 -0.07Nb3Cl8-1.0BPC melt at 10mA/cm2 and 140°C.
