炭素
Online ISSN : 1884-5495
Print ISSN : 0371-5345
ISSN-L : 0371-5345
含ケイ素高分子から合成される高耐酸化性の炭素/ケイ素/金属酸化物の複合体
伊藤 正義鈴木 大地佐々木 ユミ内田 修司成澤 雅紀
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2007 年 2007 巻 226 号 p. 32-37

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The silicon-containing thermosetting polymer, poly [(phenylsilylene) ethynylene-1, 3-phenyleneethynylene] (abbreviated as MSP), was hybridized with metal oxides, such as SiO2, TiO2, Al2O3 or B2O3 by a blending and sol-gel methods. Amorphous silicon containing carbon obtained by pyrolyzing MSP at 1000°C showed higher oxidation-resistance than the commercial amorphous carbon. The carbon-silicon-B2O3 hybrids (B2O3 8%) obtained by pyrolyzing the molding sample of MSP/B2O3 at 1000°C showed much higher oxidation-resistance than the carbon derived from MSP.
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