初期Al濃度が異なる多元系チタン合金溶湯からのAlの蒸発挙動

抄録

This study examines the evaporation of Al from a molten commercial Ti alloy with different Al concentrations after partial melting in a small electron beam furnace. Electron probe micro analysis confirmed that the Al concentration in the molten region was uniform. The movement of Al in the molten region was not found to be the rate determining step. The Al concentration in the molten region consistently decreased with an increasing melting time but in a non-linear manner. The activity of Al in the molten alloy was calculated using thermodynamic data, which indicated that it increased with an increasing Al concentration in the ingot. However, the activity of Al in the molten alloy did not increase linearly under the influence of the other alloying elements. The overall mass transfer coefficient of Al from molten alloy during evaporation increased with an increasing initial Al concentration with the mass transfer coefficient of Al depending on the activity of Al. An evaporation model was constructed by considering the mutual interaction between Al and the other alloying elements. This evaporation model was able to predict the amount of Al evaporation from the multi-component Ti alloy melt.